England were unable to cement top spot in Group after going down 1-0 to Denmark in the UEFA Nations League on Wednesday evening.
Harry Maguire was sent packing in the 31st minute following a foul on Kasper Dolberg, leaving the Three Lions with ten players.
Denmark were ahead before halftime after Christian Eriksen beat Jordan Pickford from the penalty spot after Thomas Delaney went down in the area.
Ainsley Maitland-Niles was removed soon thereafter for Tyrone Mings, with a forced change for Denmark seeing Dolberg pulled off for Pione Sisto.
The Three Lions pushed for a turnaround throughout the second half, but couldn't beat Kasper Schmeichel who in the end steered his side to victory.
Belgium returned to winning ways in their UEFA Nations League group with a 2-1 win over Iceland on Wednesday evening.
Belgium were up and running in no less than ten minutes when Lukaku bulldozed two defenders in the area to arrow into the top corner.
The Belgians were pegged back before 20 minutes when Birkir Mar Saevarsson got behind the defence to tuck beyond Mignolet after charging in the area.
Lukaku restored the Belgians lead just before halftime after winning and then stepping up to convert a penalty kick to complete his brace.
Belgium refreshed their initial line-up minutes into the second half, with Hans Vanaken replacing Leandro Trossard, as Roberto Maritnez's side ran down the rest of the minutes for the win.
Italy were condemned to back-to-back draws in the UEFA Nations League following a 1-1 stalemate against the Netherlands on Wednesday evening.
The Azzurri took the lead in less than 16 minutes from a fine finish by Lorenzo Pellegrini who combined with Barella's accurate pass.
Netherlands were level before the half-hour mark after Donny van De Beek displayed sharp reactions from close range to prod home a loose ball.
After a quiet start to the second half, the home side looked for the winner at the closing stages with a double substitution in Manuel Locatelli and Moise Kean.
This however did not materialise as it finished all square in Milan with the Dutch still searching for their first win under new boss Frank De Boer.